Understanding and controlling water stability of MOF-74

Controlling Chemical Reactions in Confined Environments: Water Dissociation in MOF-74

The confined porous environment of metal organic frameworks (MOFs) is an attractive system for studying reaction mechanisms. Compared to flat oxide surfaces, MOFs have the key advantage that they exhibit a well-defined structure and present significantly fewer challenges in experimental characterization. As an example of an important reaction, we study here the dissociation of water—which plays...

Structural and electronic properties of MOF-74

Quantum Sieving of H2 and D2 in Fe-MOF-74

Biological Stability of Drinking Water: Controlling Factors, Methods, and Challenges

Biological stability of drinking water refers to the concept of providing consumers with drinking water of same microbial quality at the tap as produced at the water treatment facility. However, uncontrolled growth of bacteria can occur during distribution in water mains and premise plumbing, and can lead to hygienic (e.g., development of opportunistic pathogens), aesthetic (e.g., deterioration...

Water Adsorption and Insertion in MOF‐5

The high surface areas and tunable properties of metal−organic frameworks (MOFs) make them attractive materials for applications in catalysis and the capture, storage, and separation of gases. Nevertheless, the limited stability of some MOFs under humid conditions remains a point of concern. Understanding the atomic-scale mechanisms associated with MOF hydrolysis will aid in the design of new c...